There are a few distinct things here. Learning 6502 assembly is straightforward, and you'd be better learning about simple (not modern) assembly languages at a high level--opcodes, registers, noop, branch, jump, compare, accumulators, program counters, and clock cycles. From there, start writing 6502 in an emulator and seeing what happens. That's where you're going to learn, and the feedback will be a lot faster. Programming for an Apple II will be more about learning how to interact with devices through memory.